Week 
CLASS LOG:
What have we learned today? 
Topic 
Homework 
1 
<Sep 12>
What's
ThermoII? Detailed summary of topics  Course action plan 
A quick Math tutorial on exact differential
<Sep 14>
Review of
ThemoI Magic square, Gibbs free energy, GibbsHelmholtz equation, van't Hoff equation 

Homework 1
Due: Sep 26
Key 
2 
<Sep 19>
 Chemical potential 
definition  The significance of chemical potential 
Partial Molar quantities
<Sep 21> Lecture
Cancelled 


3 
<Sep 26> 
Spontaneous mixing of two ideal gases  Phase equilibrium of a singlecomponent system
<Sep 28> 
The Clapeyron equation 
Four examples of applying the Clapeyron equation to SS, SL, LV and SV phase
transitions for a pure system  Connection to the ClausiusClapeyron
equation 

Homework 2
Due: XXX
Key 
4 
<Oct 3>

Type of phase transitions: 1st and 2nd order transitions

Introduction to phase equilibrium of
a binary system 
Fugacity and activity 
The significance of fugacity  Definition
of a solution  Composition of solutions
<Oct 5>
 What is an ideal solution  Raoult's law 
Phase diagram  An numerical example about ideal solutions 


5 
<Oct 10>
Fall Break  No lecture
<Oct 12>
 Features of a phase diagram of a binary solution  Binary solution 
composition diagrams 
Pressurecomposition diagrams: Evacuation curves  Temperaturecomposition
diagrams 

Homework 3
Due: XXX
Key 
6 
<Oct 17>
Comments on distillation and cooking tips  Formation of ideal solutions: 
Changes in V, H and S as a result of ideal solution formation  Dilute
solutions
<Oct
19>
Term Test #1

Everything up to and including materials covered in
Weeks 15. 



<Oct 24>
 Henry's law  Real solution
<Oct 26> 
Deviation from ideality
 DuhemMargules equation
 An example  


7 
<Oct 31>
Azeotrope 
Liquidliquid
equilibria  Upper and lower consolute temperatures  Phase diagram
 Heating and cooling curves  Eutectic point  Compound formation 
Congruent and incongruent melting
<Nov 2> 
An example of incongruent melting
 Peritectic point

Two examples of
solidsolid equilibria: ectectoids


Homework
4
Due: XXX
Key 
8 
<Nov 7>
 An extended version of the Phase Rule
 Some examples on including constraints related to independent chemical equilibria, stoichiometric relations
and electrical neutrality  Activity coefficient and chemical potential

<Nov 9>  Thermodynamics of electroytic
solutions and electrochemical cells  History of electrochemistry  Arrehnius law
 Faraday's law  Chemical potentials, activities and
activity coefficients for electrolytic solutions 
Mean activity coefficient 


9 
<Nov 14>
 DebyeHuckel
limiting law  Crash course on electrostatics  DebyeHuckel theory
 General approach 
DebyeHuckel theory  How to calculate the Mean Activity Coefficient
<Nov 16>
Term Test #2
 Everything up to and including materials covered in
Weeks 17 inclusive, with emphasis on materials not tested in Term Test #1.



10 
<Nov 21>
 Summary of DH theory  Limitations of DH theory  Basic concepts of
electrochemical cells  Potentials
<Nov 23>

Galvanic cell Standard cell  Reversible cells 

Homework
5
Due: XXX
Key 
11 
<Nov 28> 
Free energy, entropy, and enthalpy of cell reactions
<Nov 30> 
Standard emf 
Nernst equation  How to determine E^{o? }  Standard Electrode Potentials and Standard Hydrogen Electrode  An
example 






Final examination:
TBA 